Ocean acidification is sometimes called “climate change’s equally evil twin,” and for good reason: it's a significant and harmful consequence of excess carbon dioxide in the atmosphere that we don't see or feel because its effects are happening underwater. At least one-quarter of the carbon dioxide (CO2) released by burning coal, oil and gas doesn't stay in the air, but instead dissolves into the ocean. Since the beginning of the industrial era, the ocean has absorbed some 525 billion tons of CO2 from the atmosphere, presently around 22 million tons per day.
At first, scientists thought that this might be a good thing because it leaves less carbon dioxide in the air to warm the planet. But in the past decade, they’ve realized that this slowed warming has come at the cost of changing the ocean’s chemistry. When carbon dioxide dissolves in seawater, the water becomes more acidic and the ocean’s pH (a measure of how acidic or basic the ocean is) drops. Even though the ocean is immense, enough carbon dioxide can have a major impact. In the past 200 years alone, ocean water has become 30 percent more acidic—faster than any known change in ocean chemistry in the last 50 million years.
Scientists formerly didn’t worry about this process because they always assumed that rivers carried enough dissolved chemicals from rocks to the ocean to keep the ocean’s pH stable. (Scientists call this stabilizing effect “buffering.”) But so much carbon dioxide is dissolving into the ocean so quickly that this natural buffering hasn’t been able to keep up, resulting in relatively rapidly dropping pH in surface waters. As those surface layers gradually mix into deep water, the entire ocean is affected.
Such a relatively quick change in ocean chemistry doesn’t give marine life, which evolved over millions of years in an ocean with a generally stable pH, much time to adapt. In fact, the shells of some animals are already dissolving in the more acidic seawater, and that’s just one way that acidification may affect ocean life. Overall, it's expected to have dramatic and mostly negative impacts on ocean ecosystems—although some species (especially those that live in estuaries) are finding ways to adapt to the changing conditions.
However, while the chemistry is predictable, the details of the biological impacts are not. Although scientists have been tracking ocean pH for more than 30 years, biological studies really only started in 2003, when the rapid shift caught their attention and the term "ocean acidification" was first coined. What we do know is that things are going to look different, and we can't predict in any detail how they will look. Some organisms will survive or even thrive under the more acidic conditions while others will struggle to adapt, and may even go extinct. Beyond lost biodiversity, acidification will affect fisheries and aquaculture, threatening food security for millions of people, as well as tourism and other sea-related economies.
At its core, the issue of ocean acidification is simple chemistry. There are two important things to remember about what happens when carbon dioxide dissolves in seawater. First, the pH of seawater water gets lower as it becomes more acidic. Second, this process binds up carbonate ions and makes them less abundant—ions that corals, oysters, mussels, and many other shelled organisms need to build shells and skeletons.
The pH of the ocean fluctuates within limits as a result of natural processes, and ocean organisms are well-adapted to survive the changes that they normally experience. Some marine species may be able to adapt to more extreme changes—but many will suffer, and there will likely be extinctions. We can't know this for sure, but during the last great acidification event 55 million years ago, there were mass extinctions in some species including deep sea invertebrates. A more acidic ocean won’t destroy all marine life in the sea, but the rise in seawater acidity of 30 percent that we have already seen is already affecting some ocean organisms.
If the amount of carbon dioxide in the atmosphere stabilizes, eventually buffering (or neutralizing) will occur and pH will return to normal. This is why there are periods in the past with much higher levels of carbon dioxide but no evidence of ocean acidification: the rate of carbon dioxide increase was slower, so the ocean had time to buffer and adapt. But this time, pH is dropping too quickly. Buffering will take thousands of years, which is way too long a period of time for the ocean organisms affected now and in the near future.
So far, the signs of acidification visible to humans are few. But they will only increase as more carbon dioxide dissolves into seawater over time. What can we do to stop it?
What is Ocean Acidification? - NOAA Pacific Marine Environmental Laboratory (PMEL) Carbon Program
Impacts of Ocean Acidification (PDF) - European Science Foundation
Covering Ocean Acidification: Chemistry and Considerations - Yale Climate Media Forum
An Introduction to the Chemistry of Ocean Acidification (PDF) - Skeptical Science
Ocean Acidification at Point Reyes National Seashore (Video) - National Park Service
Sea Change (Seattle Times)
Bad acid trip: A beach bum’s guide to ocean acidification (Grist)
What Does Ocean Acidification Mean for Sea Life? (Ensia)
10 Key Findings From a Rapidly Acidifying Arctic Ocean (Mother Jones)
Ocean Acidification and Its Potential Effects on Marine Ecosystems - John Guinotte & Victoria Fabry (PDF)
Impacts of ocean acidification on marine fauna and ecosystem processes - Victoria Fabry, Brad Seibel, Richard Feely, & James Orr